Name | variamine blue rt salt (C.I. 37240) |
Synonyms | BlueSaltNR BluebaseRT AcnaBlueRTSalt FastbluesaltVRT DaitoBlueSaltVR FastBlueVRTSalt 4-Diazodiphenylamine Sulfate C.I.AzoicDiazoComponent22(37240) variamine blue rt salt (C.I. 37240) |
CAS | 4477-28-5 |
EINECS | 224-756-8 |
InChI | InChI=1/C12H10N3.H2O4S/c13-15-12-8-6-11(7-9-12)14-10-4-2-1-3-5-10;1-5(2,3)4/h1-9,14H;(H2,1,2,3,4)/q+1;/p-1 |
Molecular Formula | C24H22N8O4S |
Molar Mass | 518.55 |
Appearance | Powder |
Storage Condition | Room Temprature |
MDL | MFCD00011895 |
Physical and Chemical Properties | Chemical properties yellow to gray green paste. Soluble in water, soluble in ether and ethanol. It decomposes with increasing temperature. It easily turns green in the air and in light. Its solution encounters copper and iron ions and causes decomposition. It does not burn or explode at room temperature, but it cannot be dried to prevent accidents. It has a stimulating effect on the eyes, nose and respiratory tract. |
Use | Mainly used for the production of diazonium printing paper, and cotton fabric dyeing and printing. It is advisable to use color matching. |
WGK Germany | 3 |
Raw Materials | Sodium nitrite Sodium sulfide 4-Chloronitrobenzene Diphenylamine 4-Aminodiphenylamine 4-NITROSODIPHENYLAMINE |
color index | 37240 |
EPA chemical information | Benzenediazonium, 4-(phenylamino)-, sulfate (1:1) (4477-28-5) |
two methods, p-nitrochlorobenzene method and diphenylamine method, are used in China. 1. The p-nitrochlorobenzene method is obtained by condensation of p-nitrochlorobenzene with aniline and salicylic acid, then reduced and distilled by sodium sulfide, and then treated by hydrochloric acid into salt, then filtered and dried. 2. Diphenylamine method is obtained by coupling diphenylamine and aniline diazonium salt, and then hydrolytic reduction, salt formation, re-filtration and drying. Raw material consumption (kg/t)(1) p-nitrochlorobenzene method nitrochlorobenzene 1065 aniline 1200 salicylic acid 273(2) diphenylamine method diphenylamine 1180 chlorobenzene 900 methanol 570